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Which of the following is an invalid set of quantum numbers for an electron?

  • n=3, l=2, m_l=-2, m_s=+1/2.
  • n=4, l=3, m_l=0, m_s=-1/2.
  • n=2, l=2, m_l=1, m_s=+1/2.
  • n=1, l=0, m_l=0, m_s=-1/2.
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