A longer saturated hydrocarbon chain has a greater surface area for van der Waals interactions with neighboring chains, requiring more thermal energy (higher temperature) to disrupt these interactions and melt. Unsaturation, conversely, introduces kinks that lower the melting point.
A longer saturated hydrocarbon chain has a greater surface area for van der Waals interactions with neighboring chains, requiring more thermal energy (higher temperature) to disrupt these interactions and melt. Unsaturation, conversely, introduces kinks that lower the melting point.