Sucrose is dextrorotatory (+66.5°). Upon hydrolysis, the resulting fructose is strongly levorotatory (-92°), which outweighs the dextrorotation of glucose (+52.7°). The net optical rotation of the mixture (invert sugar) is negative (-19.8°), thus the rotation is inverted.
Sucrose is dextrorotatory (+66.5°). Upon hydrolysis, the resulting fructose is strongly levorotatory (-92°), which outweighs the dextrorotation of glucose (+52.7°). The net optical rotation of the mixture (invert sugar) is negative (-19.8°), thus the rotation is inverted.