Practice Questions

Evaporation is a phase transition, not a chemical reaction. The molecules are the same; they are just farther apart. The energy required (latent heat) is used exclusively to overcome the attractive forces—primarily hydrogen bonds—between the water molecules.

The dissolution of non-polar molecules in water would require water to form highly organized clathrate cages around them, causing a significant decrease in the system's entropy (ΔS < 0). This makes the process thermodynamically unfavorable, resulting in the hydrophobic effect and phase separation.

The formation of ice crystals and the 9% volume expansion upon freezing can physically rupture cell membranes and delicate tissue structures. This is the basis of frostbite and why cryoprotective agents are needed to preserve cells.

Surrounding exposed non-polar groups, water forms highly ordered, low-entropy cages. When these groups aggregate in the protein's core, this caged water is released into the bulk solution, significantly increasing its entropy. This increase in the entropy of water is a major driving force for protein folding.

As surface water cools to 4°C, it sinks, displacing warmer water until the entire lake is near 4°C. Further surface cooling creates less dense, near-freezing water that stays on top and forms ice. This insulates the dense, liquid 4°C water layer at the bottom, allowing aquatic life to survive.

All metabolic reactions occur in an aqueous medium. Freezing locks water into a solid crystalline state, drastically reducing the water available as a solvent and reactant. This halts enzyme activity and prevents microbial growth, preserving the food.

Because of its high specific heat, water can store a large amount of thermal energy for a given mass and temperature change. As it cools to body temperature, it slowly releases this stored heat, providing sustained thermal therapy.

The high surface tension of the water-based fluid lining the alveoli would cause their collapse. Type II alveolar cells secrete pulmonary surfactant, a mixture of phospholipids and proteins that intersperses between water molecules, disrupting cohesion and dramatically lowering surface tension.

A hypertonic solution has a higher solute concentration (lower water concentration/water potential) than the cell's interior. Water moves out of the cell by osmosis towards the lower water potential, causing the cell to shrink and its surface to become scalloped (crenation).

The phospholipid head groups are charged and highly polar. Water interacts favorably with these groups, forming hydrogen bonds with the oxygen atoms of the phosphate and electrostatic interactions with the charged nitrogenous base (e.g., choline). This hydration stabilizes the bilayer surface.